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Why do we need Durable Water Repellents?
Even if it employs a waterproof membrane, a garment can become saturated (soaked) when exposed to sustained moisture over time. When this happens it impedes the breathability of the membrane below the shell layer. For non-membrane fabrics, small amounts of rain can easily penetrate the fabric and get you wet.
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Waterproof vs. Water Repellent
Because they sound similar and are methods of keeping you dry, “waterproof” and “water repellent” are often used interchangeably by brands – but there is a key distinction between the two.
• Waterproof: keeping water from going through the fabric
• Water repellent/resistant: keeping water off the fabric
With enough rain, a water repellent fabric will become wet.
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Oil & water
Oil and water don’t mix because water is polar (has a + / – charge, like a magnet) and oil is not. This is the reason early methods of keeping clothes dry were through waxing, or oiling canvas to repel moisture.
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Polarity
Polarized molecules repel or attact each other, due to their electromagnetic charge. This repulsive force is critical to the function of DWRs.
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Repelling through the magnetic charge
You can turbo-charge this effect by taking advantage of the fact that water is slightly electronegative – basically, the Oxygen molecule dominates the water molecule and has a negative charge. When you have two magnets with their North or South poles facing each other, they push themselves apart. This is what happens with Perflourinated (PFC) DWRs – they work by using the Fluorine molecule to push away the Oxygen molecule due to their common negative charge.
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Contact angle
When you push away the water, it causes water to “bead up”, by increasing surface tension. The water droplets act like balls and simply roll off the fabric.
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Perfluorinated compounds
Most water repellent garments currently use PFC/PFAS (Perflourinated Carboxylic Acid) DWR. However, there is growing research that indicates PFCs can affect our endocrine / hormonal system. Thus, the industry is now moving away from PFCs, relying more on the principle of Oil & Water to keep fabric dry.
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Persistant PFCs
DWR with 8-carbons (C8-DWR) is more durable than 6-carbon DWR – but it persists in our water supply for much longer as a result.
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PFC-free DWR & sustainability
Over the past 12 months, we’ve been shifting all of our DWRs to C6 and non-PFC, Silicon-based DWRs, and our recent Mercury Jacket, Momentum Chinos, Doppler Mac and Kinetic Jacket all benefit from this change.